富豪洪飞虎（古天乐 饰）因怪病找到峨嵋派掌门王凤（郑秀文 饰），她对飞虎的生性傲慢毫无好感，于是用尽各种奇怪的方法治疗飞虎
王凤的师姐李莫愁（李冰冰 饰）突然出现，并扬言要铲除峨嵋派 未免伤及无辜，王凤尽快医好了飞虎 知道了王凤的恶作剧之后，飞虎愤然离开了
为了与师姐决战，王凤急需练好“伤心断肠剑”，但从未经历伤心之苦的她 无法领悟“百年好合”这一招式的要领，王凤在众人的劝说下决定求助与飞虎 飞虎不计前嫌，用尽办法让王凤伤心，练好招式 王凤又能否成功
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